CuFePCoSn EN: - UNS: C19500 |
High strength modified copper alloy, best combinations of electrical conductivity, mechanical strength, forming properties and stress relaxation resistance. C19500 is a precipitation-hardenable copper alloy which has an electrical conductivity of 50%IACS in the aged condition. The alloy is highly resistant to stress relaxation when used a spring under constant stress and it is expected that its creep resistance at moderately elevated temperatures will also prove to be good, has good joinability and good corrosion resistance. This alloy also exhibits good corrosion resistance making it essentially immune to stress corrosion cracking.
CuFePCoSn fits applications requiring excellent hot and cold workability as well as high strength and conductivity. C19500 is high strength, high conductivity alloy developed for applications in current carrying parts. The high strength of CuFePCoSn coupled with moderate conductivity makes this alloy use ful in spring terminal applications. Resistance to stress relaxation over time improves the life expectancy of connectors.
Sheet, strip, rolled bar, flat wire, welded tube and fabricated parts. Electrical components such as springs, contacts, connectors, terminals, clips, jaws, clamps, sockets in electro-mechanical assemblies, electronics assemblies, and wiring harness for automobiles and appliances, edge connectors for printed circuit boards, switches, integrated circuit lead frames. Literature:
Chemical composition
|
Value | Comments | |
Al [ wt.% ] | 0,2 | ||
Co [ wt.% ] | 0,6-1,0 | ||
Cu [ wt.% ] | 96,24-97,42 | Calculated | |
Fe [ wt.% ] | 1,3-1,7 | ||
P [ wt.% ] | 0,08-0,12 | ||
Pb [ wt.% ] | 0-0,02 | ||
Sn [ wt.% ] | 0,4-0,7 | ||
Zn [ wt.% ] | 0-0,02 |
Chemical composition of CuFePCoSn (C19500)
Chemical composition. wt% | ||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Ag |
Mg |
Sn |
Ni |
Si |
Cr |
Zr |
Fe |
P |
Pb |
Zn |
Co |
Al |
other |
Cu |
- |
- |
0.1-1.0 |
- |
- |
- |
- |
1.0-2.0 |
0.015-0.15 |
0.02 |
0.20 |
0.3-1.3 |
0.2 |
- |
min. 97.8 |
|
|
0.6 |
|
|
|
|
1.5 |
0.18 |
|
|
|
|
|
|
Chemical composition of CuFePCoSn (C19500)
Chemical composition. wt.% | ||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Ag |
Mg |
Sn |
Ni |
Si |
Cr |
Zr |
Fe |
P |
Pb |
Zn |
Co |
Al |
other |
Cu |
- |
- |
0.4-0.7 |
- |
- |
- |
- |
1.3-1.7 |
0.08-0.12 |
max 0.03 |
max 0.20 |
0.6-1.0 |
max 0.2 |
max.0.10 |
min. 97.8 |
Mechanical properties
|
||||||
UTS [MPa] | YS [MPa] | Elongation [%] | Hardness | Young’s modulus [GPa] | Kirchhoff’s modulus [GPa] | Poisson ratio |
350-700 | 170-650 | 2-25 | 81-90 Comments: [HRB] | 119 | No data | 0,33 |
Mechanical requirements of CuFePZnCoSn (C19500) according ASTM standards (different tempers)
Temper | Tensile strength, MPa | Yield strength 0.2%, MPa | Elongation 50, % | Hardness, HRB | Literature |
---|---|---|---|---|---|
O61 | Min. 350 | Min.170 | Min.25 | … | |
O50 | 520-590 | 395-530 | 11-17 | 81-89 | |
H02 | 565-620 | 505-605 | 3-13 | 85-88 | |
H08 | 605-670 | 585-650 | 2-5 | 87-90 | |
H10 | Min. 670 | Min.650 | Max.2 | Min.90 |
Mechanical properties of CuFePZnCoSn Alloy
Temper | Tensile strength, MPa | Yield strength, MPa | Elongation, % | Literature |
---|---|---|---|---|
Soft annealed | 360 | 172 | 25 | |
Precipitation hardened | 550 | 450 | 15 | |
PHT. CR half hard | 590 | 550 | 8 | |
PHT. CR spring | 630 | 614 | 3 | |
PHT.CR super spring | 670 | 650 | 2 | |
Note: PHT – precipitation heat treated, CR-cold rolling |
Mechanical properties of CuFe1.5P0.18Co0.8Sn0.6 (Olin 195)
Temper | Tensile strength, MPa | Elongation, % | Literature |
---|---|---|---|
Annealed | 345-415 | 26 | |
1/4 hard | 415-495 | 14 | |
1/2hard | 470-540 | 6 | |
3/4hard | 515-585 | 3 | |
Hard | 565-620 | 2 | |
Sping | 605-670 | 2 |
Mechanical properties of CuFe1.5P0.18Co0.8Sn0.6 vs temperature annealing
Temperature, °C | Tensile strength, MPa | Yield strength, MPa | A50, % |
---|---|---|---|
20 | 550 | 453 | 14.9 |
150 | 487 | 416 | 12.4 |
205 | 463 | 399 | 12.9 |
260 | 434 | 376 | 13.7 |
315 | 407 | 356 | 11.3 |
370 | 357 | 323 | 16.2 |
425 | 308 | 282 | 19.8 |
390 | 214 | 179 | 18.7 |
550 | 179 | 128 | 16 |
600 | 137 | 101 | 17 |
C19500 alloy mechanical properties vs annealing temperature
The alloy has corrosion resistance superior to that of copper when exposed to industrial. marine or industrial-marine atmospheres. It is essentially immune to stress corrosion cracking.
Type of corrosion | Suitability | Literature |
---|---|---|
Atmospheric | Good | |
Marine environment | Good | |
Stress crack | Good | |
Hydrogen embrittlement | No | |
Electrolytic | No data |
Rupture strengths of copper (C11000) and CuFePZnCoSn (19500) – 100 000h rupture strength of strip
Stress rupture strength of CuFePCoSn (C19500) strip at 260. 315.370 and 425°C
Creep rate for CuFePCoSn strip
Fatigue strength of CuFePCoSn copper alloy
Temper | Tensile strength, MPa | Fatigue strength, MPa | Literature |
---|---|---|---|
Precipitation hardened | 552 | 180 | |
PHT. CR spring | 634 | 200 |
Fabrication properties
|
Value | Comments | |
Soldering | excellent | ||
Brazing | excellent | ||
Hot dip tinning | excellent | ||
Electrolytic tinning | excellent | ||
Laser welding | good | ||
Oxyacetylene Welding | fair | ||
Gas Shielded Arc Welding | good | ||
Coated Metal Arc Welding | fair | ||
Spot Weld | fair | ||
Seam Weld | good | ||
Butt Weld | good | ||
Capacity for Being Cold Worked | excellent | ||
Capacity for Being Hot Formed | excellent | ||
Forgeability Rating | 65 | 65% of C37700 (forging brass) | |
Machinability Rating | 18 | 18% of C36000 (free-cutting brass) |
In the mill annealed condition. i.e. precipitation hardened to have a yield strength of 450 MPa. Alloy C19500 can be readily cold formed by bending. shallow stamping or deep drawing. However. only moderate stretching should be attempted. in the cold rolled tempers. a generous bending radius is desirable and parts should be designed to avoid bends parallel to the rolling direction when maximum strength is required. The alloy can be hot worked in the temperature range 650 to 980 °C.
The alloy can be joined by the inert-gas shielded metallic-arc process and by resistance welding using the seam or butt welding procedures. It has excellent solderability.
Alloy 195 has a machinability rating of 18 where free-cutting brass equals 100. In general. the most satisfactory machined surface on copper is obtained by means of high cutting speeds combined with light cuts. For turning and similar operations. speeds of about 40 to 60 m per minute may be adopted but these speeds must be reduced when employing heavy cuts. With tungsten carbide tools. considerably higher speeds can be used. Tools are commonly used with about 15 degree front clearance and 25 degree top rake. The included angle of the cutting tool must be increased for heavy work. The lubricant employed should be varied with the type of work. For heavy cuts at slow speeds. mineral oils or blended lard and mineral oils are preferable; for lighter cuts at higher speeds. emulsions are favored. Degreasing of soiled metal followed by cleaning in a dilute sulfuric acid solution will remove surface oxidation resulting from atmospheric exposure or controlled atmospheric annealing. Heavy oxide films or stains are removed by the same brightening solutions used for copper.
Technological properties
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Melting temperature [°C] | Casting temperature [°C] | Castability | Annealling temperature [°C] | Homogenization temperature [°C] | Quenching temperature [°C] | Ageing temperature [°C] | Stress relievieng temperature [°C] | Hot working temperature [°C] |
1080-1090 | No data | No data | 500-600 Comments: After cold work, annealling time: 1h | No data | 900 Comments: water quench | 450-600 Comments: Ageing time: 1h | No data | 650-980 |