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CuFe2P
EN: CW107C
UNS: C19400
MANUFACTURERS LIST
Aurubis
PNA 212
KM Europa Metal AG
STOL194, STOL79
Luvata
CuFe2P
Nexans
CuFe2P

High strength modified copper  alloy, best combinations of electrical conductivity, mechanical strength, forming properties and stress relaxation resistance.

CuFe2p fits applications requiring excellent hot and cold workability as well as high strength and conductivity. Alloy CuFe2P can be used when copper C1100 and others lack sufficient strength. Furthermore, CuFe2P resistance to softening allows it to retain strength after extended periods at elevated temperatures. CuFe2P can be selected to replece the brass alloys when improved solderability is required.

Basic properties

Basic properties
Density
[g/cm3]
Specific heat capacity
[J/(kg*K)]
Temperature coefficient of electrical resistance (0...100°C)
[10-3/K]
Electrical conductivity
[T=20°C, (% IACS)]
Thermal conductivity
[W/(m*K)]
Thermal expansion coefficient 20...300°C
[10-6/K]
8,78-8,94
380
3,3
Comments:
20-300°C
60
260
17,6

Heat capacity of CuFePZn (Fe:2,4, Zn:0,12, P:0,03%) vs temperature

Electrical conductivity requirements according standard ASTM B465

Temper

Electrical conductivty, MS/m

Electrical conductivity, % IACS

Literature

O50

37,7-43,5

65-75

O60

37,7-43,5

65-75

O61

37,7-43,5

65-75

O62

37,7-43,5

65-75

H01

Min 35

min.60

H02

Min 35

min.60

H03

Min 35

min.60

H04

Min 35

min.60

HO6

Min 35

min.60

HO8

Min 35

min.60

H10

Min 35

min.60

H14

Min 35

min.60

Electrical conductivity requirements of C19400 for lead frames

Name of alloy

Electrical conductivty, MS/m

Electrical conductivity, % IACS

Source

Lead frame alloy

Min38

Min 60

Thermal conductivity and electrical conductivity for CuFe2P (C19400) and different copper alloys

Applications

Circuit breaker components, contact springs, electrical clamps, springs, terminal, flexible hose, fuse clips, gaskets, gift hollowware, plug contacts, rivets, nit, welded condenser tubes, semiconductor lead frames, cable shielding. Literature:

Product

Specification

Bar, Rolled

ASTM B465

Plate

ASTM B465

Sheet

ASTM B465, B694

Strip

ASTM B465, B888, B694

Tube, Welded

ASME SB543

Chemical composition

Chemical composition
Value Comments
Cu [ wt.% ]97,02-97,835
Calculated
Fe [ wt.% ]2,1-2,6

P [ wt.% ]0,015-0,15

Pb [ wt.% ]0-0,03

Zn [ wt.% ]0,05-0,20

Chemical composition of CW107C according ASTM

Chemical composition, wt.%

Ag

Mg

Sn

Ni

Si

Cr

Zr

Fe

P

Pb

Zn

other

Cu

-

-

-

-

-

-

-

2.1-2.6

0.015-0.15

max. 0.03

0.05-0.20

-

min. 97.7

Chemical composition of CW107C according MATWEB

Chemical composition, wt.%

Ag

Mg

Sn

Ni

Si

Cr

Zr

Fe

P

Pb

Zn

other

Cu

-

-

max 0.03

-

-

-

-

2.1-2.6

0.015-0.15

max. 0.03

0.05-0.20

max 0.15

min. 97.0

Chemical composition of CW107C according Wieland

Chemical composition, wt.%

Ag

Mg

Sn

Ni

Si

Cr

Zr

Fe

P

Pb

Zn

other

Cu

-

-

-

-

-

-

 

2.4

0.03

-

0.12

Max 0.2

min. 97.0

Chemical composition of CW107C according KME

Chemical composition, wt.%

Ag

Mg

Sn

Ni

Si

Cr

Zr

Fe

P

Pb

Zn

other

Cu

-

Max0.1

-

-

-

-

-

2.1-2.6

0.015-0.15

-

0.05-0.20

Max 0.2

min. 97.0

Mechanical properties

Mechanical properties
UTS
[MPa]
YS
[MPa]
Elongation
[%]
HardnessYoung’s modulus
[GPa]
Kirchhoff’s modulus
[GPa]
Poisson ratio
275-570
110-480
2-30
80-170
115
44
0,33

Mechanical requirements according ASTM standards (different tempers)

Temper

Tensile strength, MPa

Yield strength 0,2%, MPa

Elongation A50, %

Literature

O61

275-435

110

10

H02

365-435

250

6

H04

415-485

365

3

H06

460-505

440

2

H08

485-525

460

2

H10

505-550

485

1

Mechanical properties of flat products, 0,64 mm thick

Temper

Tensile strength, MPa

Yield strength, 0,2%, MPa

Elongation A50 mm, %

Literature

O60

310

Max 150

Min 29

O50

345

160

6

HO4

440

435

4

HO8

490

480

2

Mechanical properties according DIN EN 12449 (R300 wall thikckness – 10 mm, R70, R420 – wall thickness 5mm)

Temper

Tensile strength, MPa

Yield strength, 0,2%, MPa

Elongation A50 mm, %

R300

310

Max 150

Min 29

R370

370

250

15

R420

440

320

5

Hardness of CW107C according DIN EN 12449 (wall thikckness – 10 mm)

Temper

Hardness, HV

Hardness, HB

 

min

max

min

max

H085

85

115

80

110

H110

110

140

105

135

H135

135

 -

130

 -

Mechanical properties of CW107C flat products Wieland

Temper

Tensile strength, MPa

Yield strength, MPa

Elongation, %

Electrical conductivty, MS/m

Literature

min

max

R300

300-340

max.240

min.20

35

41

R340

340-390

min 240

min.10

35

41

R370

370-430

min.330

min.6

35

41

R420

420-480

min.380

min.3

35

41

R470

470-530

min.440

min.4

35

41

R530

530-570

min.470

min.5

35

41

Hardness vs temper of CW107C

Temper

HV

Literature

H08

80-100

H10

100-120

H12

120-140

H13

130-150

H14

140-160

H15

150-170

Mechanical properties of CuFe1P according to SofiaMed

Temper

Tensile strength MPa

Yield strength MPa

Hardness Vickers HV

Elongation A10 %

Literature

H02/R370/HV110

370-430

330

110-140

>8

H04/R415/HV125

415-480

380

125-145

>4

H08/R480/HH140

480-525

440

140-160

>3

H10/R530/HV150

530-570

470

150-170

>3

Exploitation properties

Electrical conductivity and thermal conductivity of 19400 strip in elevated temperature (annealed temper O60)

Temperature, ?C

Thermal conductivity, W/mK

Electrical conductivity/ MS/m

20

262

37,5

50

264

35

100

268

31

200

275

25

250

278

21

Electrical conductivity and thermal conductivity vs annealing temperature according data in table

Elastic modulus vs temperature of CW107C 

Temperture, ºC

Modulus E, GPa

Literature

-200

128

-125

126

-75

124

25

121

100

118

150

116

200

114

Elastic modulus vs elevated temperature

Typical room-temperature and low-temperature (cryogenic) properties of C19400

Temperature, ?C

Tensile strength, MPa

Yield strength, MPa

Elongation, 50, %

20

325

170

28

20

405

360

15

20

455

405

10

-196

475

195

38

-196

570

425

30

-196

615

485

23

Softening Resistance: Leadframes are a perfect example of the type of processing that can cause parts to soften and subsequently fail. During packaging, they may be subjected to temperatures as high as 350°C for several minutes. Below figure shows the softening behavior of CW107C (C19400) and some other copper leadframe materials at 350°C. The resistance to softening exhibited by C19400 enables it to maintain the strength required to resist deformation in handling and automated assembly of the device onto a printed circuit board.

Softening behavior of CuFe2P and various lead frame copper alloys at 350°C 

Typical elevated temperature properties of annealed C19400 strip

Temperature, °C

Tensile strength, MPa

Yield strength, MPa

Literature

20

341

150

65

324

144

95

313

144

120

300

144

150

289

139

175

276

135

205

266

131

230

253

131

260

235

127

290

219

123

315

203

116

Tensile strength, yield strength vs annealing temperature according data in table

Typical response of C19400 strip

Temperature, °C

Tensile strength, MPa

Yield strength, MPa

Elongation, 50, %

Literature

100

460

450

3

205

450

435

5

315

440

415

9

370

415

385

12

425

415

360

14

480

400

345

16

540

385

310

17

595

350

220

23

650

315

140

33

705

310

115

34

760

305

110

36

815

305

110

36

Tensile strength, yield strength and elongation vs annealing temperature according data in table

Vickers hardness after heat treatment (Temper R420, typical values)

Softening curve of CuFe2P according Kobe

Softening characteristic at 500 °C (hard soldering, laser, resistance welding of cuFe2P, CuETP and CuZn10

DSC curves of CuFe2P (C19400) alloy with heating rate of 10 °C/min

Specimens chemical composition (see following graphs for mechanical/electrical vs temperature properties

Specimens No

Fe

P

Fe+P

% wt.

C1

0

0,00

0,00

C2

2,48

0,43

2,91

C3

2,38

0,67

3,05

C4

1,96

0,95

2,91

C5

1,52

1,44

2,96

C6

0,97

1,96

2,93

D1

3,94

0,00

3,94

D2

3,39

0,64

4,03

D3

3,18

0,90

4,08

D4

2,53

1,46

3,99

D5

1,94

2,04

3,98

Age-hardening of several Cu-F2P alloys (specimen C3)

Age-hardening of several Cu-F2P alloys (Specimen D3) 

Influence of tempering time on the hardness of specimen C3 quenched from 900°C

Influence of tempering time on the hardness of specimen D3 quenched from 900°C

Change of mechanical properties (Specimens C3)

Change of mechanical properties (Specimens D3)

NO DATA AVAILABLE

Type of corrosion

Suitability

Literature

Atmospheric

Good

Marine environment

Good

 

Stress crack

Good

 

Hydrogen embrittlement

Not resistant

 

Electrolytic

Fair

 

Stress relaxation resistance is critical to the maintenance of contact force over the life of an interconnect and therefore plays a role in the reliability of the system. Alloy C19400 has good stress relaxation resistance to temperatures of 105°C and is superior to copper C11000 and brass C26000.

Stress relaxation performance of C19400  (CW107C) (hard (HRO4) selected hard temper copper alloys at 75°C)

Stress relaxation behavior of CW107C for different temperatures. Test conditions: initial stress 65% Yield stress, time: 5000 h.

Stress vs temperature for C19400 strip

Stress remaining after 1000 hours of high performance copper alloys

Creep strength min, MPa properties of annealed C19400 strip (Stress causing creep of 0,01% per 1000h at 10000h test) -

 

Temperature, °C

120

150

175

205

230

260

290

315

Tensile strength, MPa

300

289

276

266

253

235

219

203

Creep strength, MPa

190

171

143

124

110

96

84

74

Creep strength vs temperature

Rupture stress vs temperature

Fatigue strength vs tensile strength, C19400, H04

Temper

Tensile strength, MPa

Fatigue strength, MPa

Literature

HO4

450

141

HO8

485

145

H10

505

145

H14

530

148

HO4

min 550

141

Fatigue strength vs tensile strength of C19400

Beandability

 

H01

H02

H03

H04

H06

0.10<s<0,25 mm

Transverse

0 x s

0.5 x s

0.5 x s

0.5 x s

Parallel

0 x s

0.5 x s

0.5 x s

1.0 x s

0.25<s

Transverse

0 x s

1 x s

1 x s

1.5 x s

Parallel

0 x s

1.0 x s

2.0 x s

3.0 x s

NO DATA AVAILABLE
Fabrication properties

Fabrication properties
Value Comments
SolderingExcellent

BrazingExcellent

Hot dip tinningExcellent

Electrolytic tinningExcellent

Laser weldingGood

Oxyacetylene WeldingGood

Gas Shielded Arc WeldingExcellent

Coated Metal Arc WeldingNot Recommended

Resistance weldingGood

Spot WeldNot Recommended

Seam WeldNot Recommended

Butt WeldNot Recommended

Capacity for Being Cold WorkedExcellent

Capacity for Being Hot FormedFair

Forgeability Rating65
C37700 (forging brass)
Machinability Rating20-25
C36000 (free-cutting brass)

Workability – cold working: Initial material was cold worked with rolling reduction: 20% (4.0 mm-3.18 mm), 30% (4.0 mm-2.70 mm), 50% (4.0 mm-1.94 mm), 70% (4.0 mm-1.22 mm), Then mechanical properties and electrical conductivity were investigated. The results of mechanical properties determinations are presented graphically in Fig. 19 and 20. In Fig. 19 average values of ultimate tensile strength (UTS), yield strength (YS) and elongation (A10) for initial samples (after cold rolling from 15mm to 4.0 mm and annealing) are marked on y-axis. Average UTS value was 434 MPa, average YS value was 373 MPa and average elongation A10 value was 10.8%. It was discovered, that hardness did not change significantly up to 70% of rolling reduction, and for this rolling reduction the lowest electrical conductivity was obtained.

Rolling reduction effect on ultimate tensile strength , yield strength and elongation of CuFe2P

Hardness and electrical conductivity vs rolling reduction of CuFe2P

Workability – heat treatment- [7.22]: Specimens 2 mm wide 12 mm thick and 100mm long from the middle of a 12 mm thick hot-rolled strip of C19400 alloy. Their composition: Fe:2,2, P:0,03,Zn:0,12%. The hot rolled specimens were ground to 10 mm in thickness to eliminate the oxidized layer and cold rolled to 2,5 mm in thickness by using a two –roll cold-rolling mill. Next they were solution-treated at 800°C, 900°C and 950°C by immersing them for 1 hour in salt bath and then quenched in water. Then they were cold-rolled to 1 mm in thickness. Next some specimen were not solution-treated, but instead directly cold-rolled to 1 mm in thickness. Temperature of ageing: 450, 500, 550, 600 and 650°C for 2,5,10 and 24 hours.

Variation in electrical conductivity after 1st cold rolling after solution treatment and after 2nd cold rolling

Rate of decrease in electrical conductivity vs % reduction (cold rolling) in different aging temperatures (specimens without solution treatment)

Rate of decrease in electrical conductivity vs % reduction (cold rolling) in different aging temperatures (solution treatment 950°C)

Vickers hardness after final cold-rolling as a function of reduction (without solution heat treatment)

Vickers hardness after final cold-rolling as a function of reduction (solution heat treatment – 950°C)

The sheet samples (CuFe2.2P0.05Zn0.16) with 100x10x1.6 mm in thickness were machined from the rectangular cast to solid solution under 850°C for 1 h then hot-rolling, water cooling and cold rolling. Subsequently, the samples were dealt by three-time rolling and two-time aging, that is , first cold rolling, first aging, second cold rolling, second ageing and final fine rolling to sheets about 0.2 mm in thickness and stress-release heat treatment

Table Process parameters of thermo-mechanical deformation

No

D, mm

FRT, mm

FAT, °C

SRT, mm

SAT, °C

TRT, mm

SRAT, °C

1

1.4

1.0

500

0.5

450

0.2

330

2

1.4

1.0

500

0.3

450

0.2

330

3

1.4

0.8

500

0.4

450

0.2

330

4

1.4

0.8

500

0.3

450

0.2

330

5

1.4

0.65

500

0.3

450

0.2

330

6

1.4

0.65

500

0.25

450

0.2

330

Note:

D: for the thickness of starting sample;
FRT: for the thickness of samples after first rolling;
FAT: for the first aging temperature;
SRT: for the thickness of samples after second rolling;
SAT: for the second aging temperature; TRT: for the thickness of sample after rolling;
SRAT: for the stress release annealing

The ageing temperatures of thermo-mechanical treatment 

FAT, °C

SAT, °C

FAT, °C

SAT, °C

550

500

525

500

550

475

525

475

550

450

525

450

550

425

525

425

550

500

475

475

550

475

475

450

550

450

475

425

550

425

475

 

Note: FAT: for the first ageing temperature; SAT: for the second ageing temperature

Fig. 26. Electrical conductivity of  sheets for diferent technological options

The optimized process was as follows: The strip with 1.4 mm thickness was first rolled to 1.0 mm and first aged at 5000C for 2 hours, and second rolled to 0.3 mm and second aged at 450°C for 2 hours, and finally rolled to 0.2 mm and stress-release annealed at 3000C for one hour. The related properties were shown in below table. It was found that final product with relatively good properties , such as the conductivity was  68,5 %IACS and microhardness was 149,9 HV .

The properties of C19400 alloys manufactured using the optimized process

Process

1.4 mm

1.0 mm

500°C/2h

0.3 mm

4500C/2h

0.2 mm

330°Cx1h

Conductivity, %IACS

-

-

-

62.1

69.0

67.3

68.5

Microhardness, HV

119.2

142.4

144.1

159.2

111.6

150.5

149.9

Combination properties of C19400 alloy with various finishing rolling temperatures

Finish temperature, °C

Hardness, HV

Elongation, %

Tensile strength, MPa

Electrical conductivity, %IACS

600-650

156

6.4

517

65.4

>750

161

6.9

540

68.5

Technological properties

Technological properties
Melting temperature
[°C]
Casting temperature
[°C]
CastabilityAnnealling temperature
[°C]
Homogenization temperature
[°C]
Quenching temperature
[°C]
Ageing temperature
[°C]
Stress relievieng temperature
[°C]
Hot working temperature
[°C]
1080-1090
No data No data 450-700
Comments:
1-3h

700-815
No data No data No data 200-300
Comments:
1-3h
800-900

825-950
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